Yes. You may order a Sigma SA bayonet mount ring and a Sigma SA electrical contact housing from your local Sigma parts department.
If your Canon EF mount lens is Sigma brand to begin with, it is going to be pretty easy because the screw pattern of the mounts match exactly. If your Canon EF mount lens is of some other brand, some drilling and/or soldering may be required. For example, please look at
http://forums.dpreview.com/forums/readflat.asp?forum=1027&thread=24401568
Please note that we will NOT be able to perform this modification for you or answer any questions about this modification.